UPSC IAS - 2014

Which of the following is/are the example/examples of chemical change? (1). Crystallization of sodium chloride (2). Melting of ice (3). Souring of milk Select the correct answer using the code given below.

Year Asked: 2014

A
1 and 2 only
B
3 only
C
1, 2 and 3
D
None

Correct Answer

B. 3 only

Detailed Explanation

The correct answer is B, since only souring of milk is a chemical change. Souring happens because bacteria such as Lactobacillus convert lactose (milk sugar) into lactic acid. This produces a new substance with a different chemical composition, and the change cannot be reversed by simply cooling or heating. Formation of a new substance and irreversibility are the usual markers of a chemical change.

Why the others fail:

  • Statement 1, crystallization of sodium chloride: Salt dissolved in water comes out as crystals with the same NaCl composition. Only the physical state and arrangement change, so this is a physical change.
  • Statement 2, melting of ice: H2O changes from solid to liquid, but the molecules remain H2O. This is a physical change.

The concept connects to the Class 8 and 10 chemistry basics that UPSC tests repeatedly, and in Mains it helps in discussing food processing, fermentation and dairy technology. Note that 'chemical' here does not mean 'harmful'; the question only asks whether the composition of the substance changes.

Trap: Aspirants see crystals forming or a solid turning into a liquid and call it chemical because it looks dramatic. Ask whether a new substance forms. If the chemical identity is unchanged, it is a physical change.

This question appeared in UPSC Prelims 2014 GS Paper-1.

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